Sundays 8pm to 11pm on Radio 2
Canadian singer-songwriter Hayden joined George for an intimate conversation and an exclusive acoustic performance.
Veteran actor Graham Greene was in the red chair to talk about his career and current TV show, Defiance.
Greene told George that he never intended to become an actor.
"I really didn't want to be an actor," Greene said. "I was a roadie and an audio technician. I got my first taste of acting. People sat me in a chair, they brought me water, they gave me food, they told me to come over here, stand there, and speak, then they took me back to the chair again, gave me water, more food, put me in the shade... I had the life of a dog.
"I could get used to this."