Luis Suarez could make his Barcelona debut against Real Madrid at the Santiago Bernabeu Stadium on Oct. 26.
The Spanish league announced its schedule for the 2014-15 season on Thursday, and the first "clasico" will take place shortly after the end of Suarez's four-month ban for biting an opponent at the World Cup.
Barcelona will host Real Madrid at the Camp Nou on March 22.
The season opens on Aug. 23 with Barcelona hosting Elche and Real Madrid hosting Cardoba. Defending champion Atletico Madrid will visit Rayo Vallecano.